Hollywood's Most Infamous Couples and Ugliest Breakups (2005)

Synopsis: Go beyond the gossip column headlines with this unauthorized look into the coupling and parting of Hollywood's hottest stars. With secret paparazzi film footage and candid photographs, HOLLYWOOD'S MOST INFAMOUS COUPLES AND UGLIEST... Go beyond the gossip column headlines with this unauthorized look into the coupling and parting of Hollywood's hottest stars. With secret paparazzi film footage and candid photographs, HOLLYWOOD'S MOST INFAMOUS COUPLES AND UGLIEST BREAKUPS delves deep into the tumultuous relationships of such celebrity elite as Tom and Nicole, Angelina and Billy Bob, Ben and J-Lo, and of course, Brad Pitt and Jennifer Anniston. Also making the list are such b-list romances as Paris Hilton and Rick Solomon, Dennis Rodman and Carmen Electra, and many more. [More]

Starring: Angelina Jolie, Brad Pitt, Jennifer Aniston, Jessica Simpson

Starring: Angelina Jolie, Brad Pitt, Jennifer Aniston, Jessica Simpson, Nick Lachey, Tom Cruise, Nicole Kidman, Ben Affleck, Jennifer Lopez